Reaction between NO and CO on rhodium (100): How lateral interactions lead to auto-accelerating kinetics

Reaction between NO and CO on Rh(100): how lateral interactions lead to auto-accelerating kinetics

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CO Oxidation over AuPd(100) from Ultrahigh Vacuum to Near-Atmospheric Pressures: CO Adsorption-Induced Surface Segregation and Reaction Kinetics

Polarization-modulation infrared reflection absorption spectroscopy (PM-IRAS) is used to study CO adsorption on AuPd(100) surfaces, one well-annealed such that contiguous Pd sites do not initially exist and a second ion sputtered such that contiguous Pd sites are exposed. At CO pressures e1 × 10-3 Torr, Pd segregation to the surface is found; however, it is not sufficient to form contiguous Pd ...

Two and Three-Body Interactions between CO, H2O, and HClO4

Intermolecular interactions of different configurations in the HOClO3···CO and HOClO3···H2O dyad and CO···HOClO3···H2O triad systems have been studied at MP2/6-311++G(2d,2p) computational level. Molecular geometries, binding energies, cooperative energies, many-body interaction energies, and Energy Decomposition Analysis (EDA) were eval...

Lattice‐gas model mimicking the NO+CO reaction on Pt(100)

Various NO‐reduction reactions on Pt(100) exhibit similar dynamical behavior, presumably due to an empty site requirement for NO dissociation. This motivates analysis of a lattice‐gas model which incorporates this feature, and which here is chosen to mimic the NO+CO reaction on Pt(100): both reactants adsorb at single empty sites, NO instantaneously dissociates given an adjacent empty site (and...

How does silicon lead the kinetics of the galvanizing reaction to lose its solid-solid character